Université de Bretagne Occidentale (UBO)

• RESEARCH
• MOLECULAR FLUORESCENCE
• ATOMIC FLUORESCENCE
• BIOANALYTICAL
• CHEMOMETRICS
• TEACHING

We have developed and optimized methods for trace metal analysis by laser-induced atomic fluorescence.

The atomisation is carried out by a and electrothermal system and the excitation by a Nd:YAG tuneable laser.

Environmental applications have been conducted in freshwater and seawater.

1 - Ta/NiO subwavelength bilayer for wide gamut, strong interference structural color.
David Spenato, Matthieu Dubreuil, Denis Morineau, Philippe Giamarchi, David Dekadkevi, Jean-Philippe Jay, Alain Fessant, Sylvain Rivet and Yann Le Grand.
Journal of Physics Communications, 2022, Vol 6, 035002.
https://doi.org/10.1088/2399-6528/ac59d0

2 – Imaging Time Resolved Electrothermal Atomisation Laser Excited Atomic Fluorescence Spectrometry for determination of mercury in seawater
Le Bihan A, Cabon J.Y., Deschamps L., Giamarchi P.
Analytical Chemistry, 2011, Vol 83, 4881 – 4886.
http://pubs.acs.org/doi/abs/10.1021/ac2005982

3 – Determination of iron in seawater by electrothermal atomic absorption spectrometry and atomic fluorescence spectrometry: A comparative study.
Cabon J.Y., Giamarchi P., Le Bihan A.,
Analytica Chimica Acta, 2010, Vol 664, 114-120.
http://www.sciencedirect.com/science/article/pii/S0003267010002308

4 – Study of marine pollution caused by the release of metals into seawater following acid spills.
Cabon J.Y., Giamarchi P., Le Floch S.,
Marine Pollution Bulletin, 2010, Vol 60, 998-1004.
http://www.sciencedirect.com/science/article/pii/S0025326X1000055X

5 – Study of trace metals leaching from coals into seawater.
Cabon J.Y., Burel-Deschamps L., Giamarchi P., Jaffrennou C., Bautin F.
Chemosphere, 2007, Vol 69, 1100-1110.
http://www.sciencedirect.com/science/article/pii/S0045653507004869

6 - Laser-induced fluorescence with OPO system. Part II: Direct determination of lead content in seawater by Electrothermal Atomization-Laser Excited Atomic Fluorescence(ETA-LEAF).

Giamarchi P., Burel L., Stephan L., Lijour Y., Le Bihan A.
Analytical and Bioanalytical Chemistry, 2003, Vol 375, 815-819.
http://rd.springer.com/article/10.1007/s00216-003-1795-3

7 – Molecular and atomic ultra traces analysis by laser induced fluorescence with OPO system and ICCD camera...
Burel L., Giamarchi P., Stephan L., Lijour Y., Le Bihan A.,
Talanta, 2003, Vol 60, 295-302.
http://www.sciencedirect.com/science/article/pii/S0039914003001024

8 – Direct determination of aluminium in seawater by electrothermal atomization-laser excited atomic fluorescence..
Le Bihan A., Lijour Y., Giamarchi P., Burel L., Stephan L.,
Spectrochimica Acta Part B, 2003, Vol 58, 15-26.
http://www.sciencedirect.com/science/article/pii/S0584854702002008

9 – Molecular and atomic laser-induced fluorescence with OPO system: Experimental set-up and applications.
Giamarchi P., Burel L., Stephan L., Lijour Y., Le Bihan A.,
Luminescence, 2002, Vol 17, N° 4, 277-278.

10 - Desirability approach for optimisation of electrothermal atomic absorption spectrometry factors in iron determinations
Salomon S., Giamarchi P., Le Bihan A.
Analusis, 2000, Vol 28, 575-586.
Free download : analusis.edpsciences.org/articles/analusis/pdf/2000/07/an1983.pdf

11 – Improvements in the determination of nanomolar concentrations of aluminium in seawater by electrothermal atomic absorption spectroscopy.
Salomon S., Giamarchi P., Le Bihan A., Becker-Rob H., Heitmann U.
Spectrochimica - Acta Part B, 2000, Vol 55, 1337-1350.
http://www.sciencedirect.com/science/article/pii/S0584854700002408

12 – Study of metal release in infiltration waters of a sewage field by setting up a D-optimal experimental design.
Giamarchi P., Joncourt G., Appriou P.
Analusis, 1998, N°8, Vol 26, 30-39.
Free download : analusis.edpsciences.org/articles/analusis/pdf/1998/08/m090898.pdf

13 - Electrothermic factors optimisation in electrothermal atomic absorption spectrometry via an optimal experimental design matrix.
Le Garrec H., Giamarchi P., Cabon J.Y., Le Bihan A. ,
Analytica Chimica Acta, 1998, N°368, 59-70.
http://www.sciencedirect.com/science/article/pii/S0003267098001780

14 - Spectroscopic factors optimisation in electrothermal atomic absorption spectrometry via an optimal experimental design matrix.
Le Garrec H., Giamarchi P., Cabon J.Y., Appriou P., Le Bihan A.,
Analytica Chimica Acta, 1997, N° 350, 171-182.
http://www.sciencedirect.com/science/article/pii/S000326709700305X